中国科学院长春应用化学研究所;
阴离子交换膜(AEMs)作为核心部件已被广泛应用于燃料电池、电解槽以及液流电池等多种能源转化与存储器件中，其性能直接影响这些电化学器件的性能。虽可以通过控制聚合物骨架结构以及离子基团在聚合物结构中的相对位置和分布等因素对AEMs的微相分离结构和性能进行调控，但AEMs材料通常存在多种降解途径，其离子传导率与吸水率或尺寸稳定性也存在Trade-off关系，发展综合性能优异的AEMs材料极具挑战性。文章以芴及其衍生的结构基元为核心，详细介绍了芴基结构修饰策略及其衍生物制备、芴基阴离子交换膜的聚合方法，以及芴基阴离子交换膜的微纳结构调控。文章聚焦高性能芴基AEMs新的发展趋势，尤其是近年来发展迅速的超酸催化体系制备主链非醚键的芴基AEMs材料，旨在为高性能AEMs材料的结构设计和性能调控提供参考和借鉴。
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基本信息:
DOI：10.16026/j.cnki.iea.2025010014
中图分类号:TM91;TQ425.236
引用信息:
[1]郑吉富,李胜海,张所波.高性能芴基阴离子交换膜的制备与微纳结构调控新进展[J].离子交换与吸附,2025,41(01):14-26.DOI:10.16026/j.cnki.iea.2025010014.
基金信息:
国家自然科学基金(基金号52273219,22075276,21875240,21774123,51661145024)