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金属-多酚网络(MPNs)是一种新兴的超分子配位材料，通过金属离子与天然多酚之间的定向分子配位作用构建。MPNs兼具金属离子功能特性与多酚结构的高亲和力优势，并具有独特的协同效应，其温和的合成条件、优异的生物相容性及结构稳定性，在环境领域已初步展现出显著应用价值。文章聚焦MPNs在环境领域的应用创新，系统梳理其制备方法及结构调控策略，深入分析其在污染治理、绿色能源开发、资源可持续利用等环境领域的前沿应用案例及独特优势，重点探讨MPNs在污染物靶向吸附、催化降解、油水分离、电池电极材料开发中的相关作用机制，为揭示MPNs在环境领域的应用潜力提供理论参考，同时剖析MPNs材料体系优化升级面临的关键挑战，以期推动其在环境领域的进一步发展和应用，为解决当前环境问题提供新的思路和方法。
Abstract：Metal-phenolic networks(MPNs) as an emerging supramolecular coordination material, are constructed through directed molecular coordination between metal ions and natural polyphenols. They combine the functional characteristics of metal ions with the high affinity advantages of polyphenol structures and have a unique synergistic effect. With their mild synthesis conditions, excellent biocompatibility, and structural stability, they have initially demonstrated significant application value in the environmental field. This paper focuses on the innovative applications of MPNs in the environmental field, systematically reviews their preparation methods and structural regulation strategies, and deeply analyzes their cutting-edge application cases and future development directions in pollution control, green energy development, and sustainable resource utilization. The unique mechanisms of MPNs in targeted adsorption of pollutants, catalytic degradation, oil-water separation and development of battery electrode materials are discussed in detail. This provides a theoretical reference for revealing the application potential and challenges of MPNs in the environmental field. At the same time, the key challenges faced by the optimization and upgrading of the MPNs material system are analyzed, in order to promote its further development and application in the field of environment, and provide new ideas and methods for solving current environmental problems.
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基本信息:
DOI：10.16026/j.cnki.iea.2026020121
中图分类号:O641.3;X505
引用信息:
[1]郭佳琪,邱慧.金属-多酚网络的制备及在环境领域的应用进展[J].离子交换与吸附,2026,42(02):121-136.DOI:10.16026/j.cnki.iea.2026020121.
基金信息:
江苏省自然科学基金(项目号BK20211286)
2026-04-20
2026-04-20