| 496 | 6 | 404 |
| 下载次数 | 被引频次 | 阅读次数 |
本文总结了铁基材料去除水中磷酸盐的相关研究进展。基于铁基材料的物化性能，阐述了铁基材料与磷酸盐之间的反应机理，主要包括络合沉淀、吸附和配体交换等，并列举了铁基材料除磷的实际应用及其修饰和改性方法。分析了铁基材料对磷的去除效果和影响因素，最后展望了铁基材料在除磷研究方面的发展方向。
Abstract：The article reviewed the progress on removal of phosphate salts from water by Fe-based materials.Based on the physical and chemical properties of Fe-based materials, the underlying mechanism for the complexation of Fe-based materials with phosphate salts was elucidated, including complex precipitation,adsorption and ligand exchange. The application, modification and optimization methods for phosphorus removal by Fe-based materials were outlined. The removal effect of Fe-based materials on phosphorus and the influencing factors were thorough discussed. Finally, the development direction of iron-based materials for phosphorus removal is prospected.
1 ROSEMARIN A, MACURA B, CAROLUS J, BARQUET K, EK F, J?RNBERG L, LORICK D,JOHANNESDOTTIR S, PEDERSEN S M, KOSKIAHO J, HADDAWAY N R, OKRUSZKO T. Circular nutrient solutions for agriculture and wastewater-a review of technologies and practices[J]. Current Opinion in Environmental Sustainability, 2020, 45:78-91.
2 LIU H, LIU Q, ZHAO J, ZHANG X, DING L, LIU Y, FU G. Spatiotemporal variation of phosphorus use efficiency across 70 lakes in China:implications for lake eutrophication management[J]. Ecological Indicators,2022, 142:109293.
3 ZHANG Q, SANG Z, LI Q, GONG J, PENG X, LI L, ZHANG Z, ZHANG B, LI S, YANG X. Facile fabrication of La/Ca bimetal-organic frameworks for economical and efficient remove phosphorus from water[J]. Journal of Molecular Liquids, 2022, 356:119024.
4 中国环境科学研究院.地表水环境质量标准[Z].国家环境保护总局;国家质量监督检验检疫总局. 2002
5 游俊仁,林木兰,汪惠阳.高浓度含磷废水处理方法综述[J].化学工程与装备, 2010,(8):143-146.
6 POPOVI?N, PR?ULJ D, MLADENOVI?M, PRODANOVI?O, ECE S, ILI??UR?I?K, OSTAFE R,FISCHER R, PRODANOVI?R. Immobilization of yeast cell walls with surface displayed laccase from streptomyces cyaneus within dopamine-alginate beads for dye decolorization[J]. International Journal of Biological Macromolecules, 2021, 181:1072-1080.
7 WANG B, WAN Y, ZHENG Y, LEE X, LIU T, YU Z, HUANG J, OK Y S, CHEN J, GAO B. Alginate-based composites for environmental applications:a critical review[J]. Critical Reviews in Environmental Science and Technology, 2019, 49(4):318-356.
8 ZHAI R, CHEN X, JIN M, HU J. Synthesis of a polydopamaine nanoparticle/bacterial cellulose composite for use as a biocompatible matrix for laccase immobilization[J]. Cellulose, 2019, 26(15):8337-8349.
9 邢亚欣,左志强,张琦,唐颖栋,杨浩铭,包晗,刘春,刘艳臣.铁基材料在城市水处理中的应用[J].给水排水,2023, 59(5):178-186.
10 郑雯佳,孙继成,王巧英,张杰,吴志超.基于膜分离的铁盐除磷效果影响因素[J].净水技术, 2023, 42(4):86-94 +136.
11 任杰,高博强,唐宇农,李爱民,杨琥. FeCl3与接枝型淀粉改性絮凝剂联用“化学沉淀-絮凝”工艺除磷去浊性能[J].环境化学, 2020, 39(11):2988-2998.
12 杜以村,丛文洁,齐升东,王德举.絮凝沉淀法处理磷酸盐废水的研究[J].能源化工, 2020, 41(5):39-43.
13 ZHANG M, ZHENG K, JIN J, YU X, QIU L, DING S, LU H, CAI J, ZHENG P. Effects of Fe(II)/P ratio and pH on phosphorus removal by ferrous salt and approach to mechanisms[J]. Separation and Purification Technology,2013, 118:801-805.
14 张琦,王亚娥,李杰.铁在脱氮除磷中的应用研究进展[J].石油化工应用, 2022, 41(8):1-8+19.
15 KONADU-AMOAH B, HU R, NDE-TCHOUPE A I, GWENZI W, NOUBACTEP C. Metallic iron(Fe-0)-based materials for aqueous phosphate removal:a critical review[J]. Journal of Environmental Management, 2022, 315:115.
16 SLEIMAN N, DELUCHAT V, WAZNE M, MALLET M, COURTIN-NOMADE A, KAZPARD V, BAUDU M.Phosphate removal from aqueous solutions using zero valent iron(ZVI):influence of solution composition and ZVI aging[J]. Colloids and Surfaces A-physicochemical and Engineering Aspects, 2017, 514:1-10.
17 LUO X, GUO X, XIA X, ZHANG X, MA N, LENG S, ULLAH S, AYALEW Z M. Rapid and long-effective removal of phosphate from iron in combination with hypochlorite(ZVI/NaClO)[J]. Chemical Engineering Journal, 2020, 382:122835.
18 NAGOYA S, NAKAMICHI S, KAWASE Y. Mechanisms of phosphate removal from aqueous solution by zerovalent iron:a novel kinetic model for electrostatic adsorption, surface complexation and precipitation of phosphate under oxic conditions[J]. Separation and Purification Technology, 2019, 218:120-129.
19 LANET P, DELUCHAT V, BAUDU M. Relevant design parameters for a reactor used in P removal with ZVIbased materials[J]. Journal of Industrial and Engineering Chemistry, 2021, 104:8-21.
20 WEN Z, LU J, ZHANG Y, LIAO X, CHENG G, CHEN R. Enhanced phosphate removal from water by using nanoscale zerovalent iron/rectorite nanocomposite(nZVI/REC):mediation role of nitrate[J]. Separation and Purification Technology, 2023, 307:122803.
21 ZHAO Y, LI Q, SHI Q, XI B, ZHANG X, JIAN Z, ZHOU G, MENG X, MAO X, KANG D, GONG B.Mechanisms of phosphate removal by micron-scale zero-valent iron[J]. Separation and Purification Technology,2023, 319:123706.
22 ZHANG Q, LI J, CHEN D, XIAO W, ZHAO S, YE X, LI H. In situ formation of Ca(OH)2 coating shell to extend the longevity of zero-valent iron biochar composite derived from Fe-rich sludge for aqueous phosphorus removal[J]. Science of The Total Environment, 2023, 854:158794.
23 练依宁,吴红斌,蔡金水,龚斌,康得军,简志强,龚亚萍,吕茳芏.杭锦土负载硫化零价铁的研制及除磷性能[J].环境工程技术学报, 2022, 12(1):127-136.
24 范晨,孟家琪,郭波.膨胀珍珠岩负载纳米零价铁高效除磷的研究[J].现代化工, 2023, 43(2):117-122+127.
25 MOHARAMI S, JALALI M. Effect of TiO2, Al2O3, and Fe3O4 nanoparticles on phosphorus removal from aqueous solution[J]. Environmental Progress&Sustainable Energy, 2014, 33(4):1209-1219.
26 贺山明,罗碧云,徐国钻,黄超,刘德刚,梁勇.用Fe3O4从钨冶炼废水中去除磷的试验研究[J].湿法冶金,2020, 39(6):543-545.
27 白润英,刘建明,郝俊峰,徐慧,胡文斌,宋蕾,刘宇红,李会东,周琦善.钙掺杂四氧化三铁回收水中磷的实验[J].环境科学, 2019, 40(9):4098-4104.
28 LIN Z, CHEN J. Magnetic Fe3O4@MgAl-LDH@La(OH)3 composites with a hierarchical core-shell structure for phosphate removal from wastewater and inhibition of labile sedimentary phosphorus release[J]. Chemosphere,2021, 264:128551.
29 LI S, ZHANG Y, QIAO S, ZHOU J. MgO coated magnetic Fe3O4@SiO2 nanoparticles with fast and efficient phosphorus removal performance and excellent pH stability[J]. Chemosphere, 2022, 307:135972.
30 崔琪瑶,孙宏浩. Fe3O4@SiO2与PAC、PAM联合去除污水中磷的研究[J].化工新型材料, 2018, 46(11):274-277.
31 JIANG H, ZHONG Y, TIAN K, PANG H, HAO Y. Enhanced photocatalytic degradation of bisphenol a over N,Sdoped carbon quantum dot-modified MIL-101(Fe)heterostructure composites under visible light irradiation by persulfate[J]. Applied Surface Science, 2022, 577:151902.
32 XIE Q, LI Y, LV Z, ZHOU H, YANG X, CHEN J, GUO H. Effective adsorption and removal of phosphate from aqueous solutions and eutrophic water by Fe-based MOFs of MIL-101[J]. Scientific Reports, 2017, 7:3316.
33 LIU R, CHI L, WANG X, WANG Y, SUI Y, XIE T, ARANDIYAN H. Effective and selective adsorption of phosphate from aqueous solution via trivalent-metals-based amino-MIL-101 MOFs[J]. Chemical Engineering Journal, 2019, 357:159-168.
34 LI Y, XIE Q, HU Q, LI C, HUANG Z, YANG X, GUO H. Surface modification of hollow magnetic Fe3O4@NH2-MIL-101(Fe)derived from metal-organic frameworks for enhanced selective removal of phosphates from aqueous solution[J]. Scientific Reports, 2016, 6:30651.
35 NEHRA M, DILBAGHI N, SINGHAL N K, HASSAN A A, KIM K-H, KUMAR S. Metal organic frameworks MIL-100(Fe)as an efficient adsorptive material for phosphate management[J]. Environmental Research, 2019,169:229-236.
36 WANG J, XIA Y. Fe-substituted isoreticular metal-organic framework for efficient and rapid removal of phosphate[J]. ACS Applied Nano Materials, 2019, 2(10):6492-6502.
37 WU Y, LIU Z, BAKHTARI M F, LUO J. Preparation of GO/MIL-101(Fe, Cu)composite and its adsorption mechanisms for phosphate in aqueous solution[J]. Environmental Science and Pollution Research, 2021, 28(37):51404-51404.
38 ZHOU R-Y, YU J-X, CHI R-A. Selective removal of phosphate from aqueous solution by MIL-101(Fe)/bagasse composite prepared through bagasse size control[J]. Environmental Research, 2020, 188:109817.
39 孙绪兵,高天,由耀辉.单宁酸铁和单宁酸亚铁对磷的吸附特性[J].皮革科学与工程, 2020, 30(5):9-15+32.
40 WANG C, LI W, ZHAO X, CHEN Z, LI Y, WANG G, DOU X. Phosphate adsorption on amorphous aluminum hydroxide-yielded transition aluminas:insights on fundamental chemistry and making engineering adsorbents[J].Journal of Water Process Engineering, 2023, 53:103677.
41 RANI L, KAUSHAL J, SRIVASTAV A L, MAHAJAN P. A critical review on recent developments in MOF adsorbents for the elimination of toxic heavy metals from aqueous solutions[J]. Environmental Science and Pollution Research, 2020, 27(36):44771-44796.
42 WANG D, CHEN N, YU Y, HU W, FENG C. Investigation on the adsorption of phosphorus by Fe-loaded ceramic adsorbent[J]. Journal of Colloid and Interface Science, 2016, 464:277-284.
43 罗紫芬.金属有机骨架材料在水处理中的应用研究进展[J].中国资源综合利用, 2022, 40(10):93-95.
44 ZHANG P, HE M, HUO S, LI F, LI K. Recent progress in metal-based composites toward adsorptive removal of phosphate:mechanisms, behaviors, and prospects[J]. Chemical Engineering Journal, 2022, 446:137081.
45 YANG Y, LI T, ZHENG Z, GE F, XU Y. Controlled mechanism and removal performance of phosphorus in black and odorous water bodies by Fe-based layered double hydroxides[J]. Journal of Environmental Chemical Engineering, 2023, 11(5):110323.
46 ZHU W, WANG R, TANG Q, ZHANG Z, YIN Z, YANG Z, YANG W. Renewable adsorbents for selective phosphorus removal:Co(OH)2-derived ZIF-67 on anion exchange resin[J]. Langmuir, 2023, 39(25):8760-8768.
47 ZHANG Y, QIN J, WANG X, CHEN Z, ZHENG X, CHEN Y. Advanced treatment of phosphorus-containing tail water by Fe-Mg-Zr layered double hydroxide beads:performance and mechanism[J]. Journal of Environmental Management, 2021, 296:113203.
48 陈鹏,李俊峰,王健康,曲文颖,谷天天,陈翠忠.三种金属阳极电絮凝法除磷效果对比实验研究[J].水处理技术, 2022, 48(8):44-47+53.
49 GUO K, SONG Z, TANG C. Remediation of PO43-in water using biodegradable materials embedded with lanthanum oxide nanoparticles[J]. Water, 2022, 14(10):1656.
50 CAI H, BAO H, ZHANG X, LEI L, XIAO C. Highly efficient sorption of selenate and selenite onto a cationic layered single hydroxide via anion exchange and inner-sphere complexation[J]. Chemical Engineering Journal,2021, 420:129726.
51 LI S, LIU M, YIN C, CHEN J, YANG X, WANG S. Tuning the structure flexibility of metal-organic frameworks via adjusting precursor anionic species for selective removal of phosphorus[J]. Process Safety and Environmental Protection, 2020, 143:322-331.
52 KORKMAZ M, OZMETIN E, SUZEN Y, CALGAN E, OZMETIN C. A new adsorbent(aluminum modified talc)for phosphate removal from alkaline solutions and optimization of data by central composite design[J].Desalination and Water Treatment, 2022, 245:178-190.
53 丁子卯,刘子森,邹羿菱云,王柔,吴振斌,张义.改性吸附材料选择性吸附除磷研究进展[J].净水技术, 2022,41 (6):7-14+110.
54 LU W, YUAN D, SCULLEY J, ZHAO D, KRISHNA R, ZHOU H-C. Sulfonate-grafted porous polymer networks for preferential CO2 adsorption at low pressure[J]. Journal of the American Chemical Society, 2011, 133(45):18126-18129.
55 AI D, WEI T, MENG Y, CHEN X, WANG B. Ball milling sulfur-doped nano zero-valent iron@biochar composite for the efficient removal of phosphorus from water:performance and mechanisms[J]. Bioresource Technology,2022, 357:127316.
56 商丹红,包敏.铁基膨润土对水中磷酸根的吸附热力学及动力学研究[J].环境工程学报, 2014, 8(5):1982-1986.
57 YAN C, JIN J, WANG J, ZHANG F, TIAN Y, LIU C, ZHANG F, CAO L, ZHOU Y, HAN Q. Metal-organic frameworks(MOFs)for the efficient removal of contaminants from water:underlying mechanisms, recent advances, challenges, and future prospects[J]. Coordination Chemistry Reviews, 2022, 468:214595.
58 崔小梅,李白雪,韩钰荧,黄亚奇,韩超,刘鉴仪,张伟.磁性铁基复合氧化物对水中磷吸附效能、机制的研究[J].鲁东大学学报(自然科学版), 2022, 38(2):179-186.
59 KUMAR I A, MEZNI A, PERIYASAMY S, VISWANATHAN N. Development of cerium-trimesic acid complexed 2D frameworks for effective nitrate and phosphate remediation[J]. Journal of Molecular Structure,2022, 1250(3):131873.
60 LIU Y, ZHONG D, XU Y, CHANG H, DONG L, HAN Z, LI J, ZHONG N. Adsorption of phosphate in water by La/Al bimetallic-organic frameworks-chitosan composite with wide adaptable pH range[J]. Journal of Environmental Chemical Engineering, 2023, 11(5):110309.
61 ZHONG X, LIANG W, WANG H, XUE C, HU B. Aluminum-based metal-organic frameworks(CAU-1)highly efficient UO22+and TcO4-ions immobilization from aqueous solution[J]. Journal of Hazardous Materials, 2021,407:124729.
62 LONG F, GONG J-L, ZENG G-M, CHEN L, WANG X-Y, DENG J-H, NIU Q-Y, ZHANG H-Y, ZHANG X-R.Removal of phosphate from aqueous solution by magnetic Fe-Zr binary oxide[J]. Chemical Engineering Journal,2011, 171(2):448-455.
63 SOLIEMANZADEH A, FEKRI M. Synthesis of clay-supported nanoscale zero-valent iron using green tea extract for the removal of phosphorus from aqueous solutions[J]. Chinese Journal of Chemical Engineering, 2017, 25(7):924-930.
64 LI S, ZHANG Y, QIAO S, ZHOU J. Green water-etching synthesized La-MIL-101(Fe)-NH2@SiO2 yolk-shell nanocomposites with superior pH stability for efficient and selective phosphorus recovery[J]. Journal of Water Process Engineering, 2023, 53:103821.
65 AWUAL M R, SHENASHEN M A, JYO A, SHIWAKU H, YAITA T. Preparing of novel fibrous ligand exchange adsorbent for rapid column-mode trace phosphate removal from water[J]. Journal of Industrial and Engineering Chemistry, 2014, 20(5):2840-2847.
66 KOILRAJ P, SASAKI K. Selective removal of phosphate using La-porous carbon composites from aqueous solutions:batch and column studies[J]. Chemical Engineering Journal, 2017, 317:1059-1068.
67 ZHAN Y, QIU B, LIN J. Effect of common ions aging treatment on adsorption of phosphate onto and control of phosphorus release from sediment by lanthanum-modified bentonite[J]. Journal of Environmental Management,2023, 341:118109.
68 WANG Y, ZHAO W, QI Z, ZHANG L, ZHANG Y, HUANG H, PENG Y. Designing ZIF-8/hydroxylated MWCNT nanocomposites for phosphate adsorption from water:capability and mechanism[J]. Chemical Engineering Journal, 2020, 394:124992.
69 HU K, LI W, MU H, REN S, ZHU H, ZENG K, WANG B, LIANG J, ZHANG Q, YANG L, ZHAO W, XIAO J.In-situ anaerobic treatment removes the passivation layer of sponge iron to restore the nitrogen and phosphorus removal performance of SBR[J]. Process Safety and Environmental Protection, 2023, 174:79-94.
基本信息:
DOI：10.16026/j.cnki.iea.2024010061
中图分类号:X703
引用信息:
[1]杨旸,侯成,江心白,等.铁基材料除磷性能及影响因素研究进展[J].离子交换与吸附,2024,40(01):61-71.DOI:10.16026/j.cnki.iea.2024010061.
基金信息:
国家自然科学青年基金(基金号52200099)
2024-02-20
2024-02-20