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1987, 06, 45-50
衣康酸双烯丙酯交联的吸附树脂的合成及极性研究
基金项目(Foundation): 国家自然科学基金
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摘要:

用衣康酸双烯丙酯作交联剂合成以丙烯酸甲酯为骨架的吸附树脂。按照通常方法,测定了它们的比表面积、堆积密度、骨架密度。找到了合成吸附树脂的合适条件。用反相色谱的方法研究了吸附树脂的极性,测定了它对几种小分子的吸附热。由此提出该树脂是一种中等极性中等比表面积的大孔吸附树脂。同时,为树脂的极性研究提供了一种方法。

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Abstract:

Adsorption resins were synthesized from methyl methacrylate with diallylita-conate as crosslinking agent. Their specific surface areas and apparent and skeletal densities were determined according to conventional methods.We found the optimal conditions under which the resins were prepared.we also investigated the polarity of these adsorption resins by inverse gas chromatography.The adsorption heats for some probe molecules were determined at the same time. The resin prepared was macroporous adsorption resin which has intermediate polarity and specific surface area

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参考文献

[1] 何炳林,石油化工,6(5) ,266(1977)

[2] Rohm and Haas Company, Summary Bulletin Amberlite Poleymeric Adsorbents, 1978

[3] 徐荣南,范培萍等,中极性吸附树脂--Amberlite XAD-7的性质与应用,全国第二次离子交换与吸附科学技术讨论会论文予印集(1986年10月,泉州)

[4] 徐荣南,孙家俊,陆妙龙,张金林,李讽英,上海师范大学报(自然科学版).4,53,(1980)

[5] 华东师大化学系高分子化学教研室 高分子化学实验(物理部分)(1982)

[6] 孙佳径 气相色谱原理分析与技术 化学工业出版社(1979)

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[1]范培萍,徐荣南,严隽坦,周培庆,严俊.衣康酸双烯丙酯交联的吸附树脂的合成及极性研究[J].离子交换与吸附,1987(06):45-50.

基金信息:

国家自然科学基金

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