2013 01 v.29 86-96
二氧化钛光催化材料及其改性技术研究进展
基金项目(Foundation):
中科院“西部之光”项目(No.RCPY201103);;
中科院“百人计划-引进国外杰出人才”启动项目资助
邮箱(Email):
DOI:
10.16026/j.cnki.iea.2013.01.006
中文作者单位:
中国科学院新疆理化技术研究所环境科学与技术研究室;中国科学院大学;
摘要(Abstract):
二氧化钛(TiO2)光催化技术作为一种绿色、洁净、节能的技术,在污染物治理、光分解水制氢、抗菌环保等领域有着广泛的应用。然而TiO2材料本身大的禁带宽度(Eg=3.2eV)阻碍了其实际应用,进而导致其可见光利用率低、量子产率低。因此制备具有高量子产率且对可见光有快速响应能力的TiO2已成为当前光催化剂研究的关键课题。国内外关于TiO2光催化剂的改性技术逐渐完善并在制备方法、材料形貌和结构控制等方面有新的突破。本文综述了TiO2光催化的制备方法及其反应机理,总结了提高TiO2光催化性能的技术路线,阐明了针对TiO2改性的各种方法的原理及关键技术,同时对TiO2光催化技术存在的问题和发展前景进行了分析和展望。
关键词(KeyWords):
二氧化钛(TiO2);;光催化技术;;可见光;;量子产率
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[23]Kudo A,Miseki Y.Chemical Society Reviews[J].2009,38(1):253-278.
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[28]夏启斌,李忠,奚红霞,等.离子交换与吸附[J].2005,21(3):216-223.
[29]耿静漪,朱新生,杜玉扣.无机化学学报[J].2012,28(2):357-361.
[30]Chen H,Chen S,Quan X,et al.The Journal of Physical Chemistry C[J].2008,112(25):9285-9290.
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[33]Su C Y,Liu L,Zhang M Y,et al.Crystal Engineering Communication[J].2012,14(11):3989-3999.
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[65]Li H X,Bian Z F,Zhu J,et al.Journal of the American Chemical Society[J].2007,129(27):8406-8407.
[66]Liu R,Sen A.Journal of the American Chemical Society[J].2012,DOI:10.1021/ja211932b.
基本信息:
DOI：10.16026/j.cnki.iea.2013.01.006
中图分类号:O643.36;O614.411
引用信息:
[1]陈琳,杨苏东,王传义等.二氧化钛光催化材料及其改性技术研究进展[J].离子交换与吸附,2013,29(01):86-96.DOI:10.16026/j.cnki.iea.2013.01.006.
基金信息:
中科院“西部之光”项目(No.RCPY201103);; 中科院“百人计划-引进国外杰出人才”启动项目资助
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