nav emailalert searchbtn searchbox tablepage yinyongbenwen piczone journalimg searchdiv qikanlogo popupnotification paper
2025 01 v.41 1-13
COF均孔树脂研究和产业化进展

Summary

Note: Please note that the following content is generated by AI. CNKI does not take any responsibility related to this content.
基金项目(Foundation): 国家自然科学基金(基金号22001131)
邮箱(Email): zhangzhenjie@nankai.edu.cn.;
DOI: 10.16026/j.cnki.iea.2024010041
中文作者单位:

耀科新材料(天津)有限公司;耀科新材料(苏州)有限公司;南开大学化学学院;

摘要(Abstract):

共价有机框架材料(COF)均孔树脂具有大比表面积、高化学稳定性以及易调节的孔结构(孔大小、孔形状、官能团),在吸附分离领域中展现出广阔的应用前景。文章总结了传统吸附分离树脂与COF均孔树脂的特点和区别,以及国内外COF均孔树脂的研究和产业化现状,分析了其大规模生产和成型过程中面临的主要技术挑战,并对COF均孔树脂的未来发展方向进行了展望,为进一步推动其产业化进程和市场应用指明了方向。

关键词(KeyWords): 均孔树脂;共价有机框架材料;熔融绿色合成;工业应用
参考文献

1 Jiang D,Covalent organic frameworks:An amazing chemistry platform for designing polymers[J].Chem,2020,6(10):2461-2483.

2 He L,Liu S,Chen L,et al.Mechanism unravelling for ultrafast and selective 99Tc O4-uptake by a radiationresistant cationic covalent organic framework:A combined radiological experiment and molecular dynamics simulation study[J].Chemical Science,2019,10(15):4293-4305.

3 Wang Y,Xie M,Lan J,et al.Radiation controllable synthesis of robust covalent organic framework conjugates for efficient dynamic column extraction of 99Tc O4-[J].Chem,2020,6(10):2796-2809.

4 Ji Z,Wang H,Canossa S,et al.Pore chemistry of metal-organic frameworks[J].Advanced Functional Materials,2020,30 (41):2000238.

5郑明月,卢国胜.MOF新材料产业现状及发展策略[J].新材料产业,2022(2):34-36.

6 Zhang P,Wang Z,Yang Y,et al.Melt polymerization synthesis of a class of robust self-shaped olefin-linked COFfoams as high-efficiency separators[J].Science China Chemistry,2022,65(6):1173-1184.

7 Zhang P,Wang Z,Wang S,et al.Fabricating industry-compatible olefin-linked COF resins for oxoanion pollutant scavenging[J].Angewandte Chemie International Edition,2022,61(52):e202213247.

8 Song Y,Sun Q,Aguila B,et al.Opportunities of covalent organic frameworks for advanced applications[J].Advanced Science,2019,6(2):1801410.

9 Pan Y,Liu H,Huang Z,et al.Membranes based on covalent organic frameworks through green and scalable interfacial polymerization using ionic liquids for antibiotic desalination[J].Angewandte Chemie International Edition,2024,63(4):e202316315.

10 Ding C,Du Y,Agarwal S.Open-cell robust COF-nanowire network sponges as sustainable adsorbent and filter[J].Advanced Functional Materials,2023,34(3):2309938.

11 Karak S,Dey K,Banerjee R.Maneuvering applications of covalent organic frameworks via frameworkmorphology modulation[J].Advanced Materials,2022,34(49):e2202751.

12 Mao T,Liu Z,Guo X,et al.Engineering covalent organic frameworks with polyethylene glycol as self-sustained humidity-responsive actuators[J].Angewandte Chemie International Edition,2023,62(4):e202216318.

13 Guan X,Chen F,Qiu S,et al.Three-dimensional covalent organic frameworks:From synthesis to applications[J].Angewandte Chemie International Edition,2023,62(3):e202213203.

14尹志义,郭为磊,王丽欣,等.离子交换树脂在天然药物化学中的应用进展[J].化学工程与装备,2023(3):197-199.

15刘永峰,郝丽云,魏鉴腾,等.共价有机骨架材料在天然产物中的应用[J].鲁东大学学报,2023,39(4):311-321.

16从毛勉,盛方标,范鲁雁.大孔吸附树脂在分离纯化中药复方中的应用[J].安徽医药,2009,13(11):1411-1414.

17王蔚,王春红,袁直.吸附树脂在生物医药领域的应用[J].化学教育,2021,42(18):18-23.

18 Wei J,Shao X,Guo J,et al.Rapid and selective removal of aristolochic acid I in natural products by vinylenelinked i COF resins[J].J Hazard Mater,2024,461:132140.

19 Zhang S,Zheng Y,Sun W,et al.Customized anion-exchange covalent organic frameworks for efficient extraction of natural products[J].Separation and Purification Technology,2024:342.

20王佳,刘建宇,刘彩琴,等.金属氧化物改性离子交换树脂去除水中重金属的研究进展[J].化学工程师,2023,37(10):75-78.

21王林江,佟建超.离子交换树脂在废水处理中的应用[J].化工设计通讯,2022,48(9):179-181.

22 Ding S,Dong M,Wang Y,et al.Thioether-based fluorescent covalent organic framework for selective detection and facile removal of mercury(II)[J].Journal of the American Chemical Society,2016,138(9):3031.

23 Cui F Z,Liang R R,Qi Q Y,et al.Efficient removal of Cr(VI) from aqueous solutions by a dual-pore covalent organic framework[J].Advanced Sustainable Systems,2019,3(4):1800150.

24 Sun Q,Aguila B,Perman J,et al.Postsynthetically modified covalent organic frameworks for efficient and effective mercury removal[J].Journal of the American Chemical Society,2017,139(7):2786-2793.

25 Singh B K,Hafeez M A,Kim H,et al.Inorganic waste forms for efficient immobilization of radionuclides[J].ACS ES&T Engineering,2021,1(8):1149-1170.

26 Liu T,Zhao Y,Song M,et al.Ordered macro-microporous single crystals of covalent organic frameworks with efficient sorption of iodine[J].Journal of the American Chemical Society,2023,145(4):2544-2552.

27 Xie Y,Pan T,Lei Q,et al.Efficient and simultaneous capture of iodine and methyl iodide achieved by a covalent organic framework[J].Nature Communications,2022,13(1):2878.

28 Wang Y,Lan J,Yang X,et al.Superhydrophobic phosphonium modified robust 3D covalent organic framework for preferential trapping of charge dispersed oxoanionic pollutants[J].Advanced Functional Materials,2022,32(36):2205222.

29 Kang K,Liu S,Zhang M,et al.Fast room-temperature synthesis of an extremely alkaline-resistant cationic metalorganic framework for sequestering Tc O4-with exceptional selectivity[J].Advanced Functional Materials,2022,32(48):2208148.

30 Jin F,Lin E,Wang T,et al.Bottom-up synthesis of 8-connected three-dimensional covalent organic frameworks for highly efficient ethylene/ethane separation[J].Journal of the American Chemical Society,2022,144(12):5643-5652.

31 Wang Z,Zhang Y,Lin E,et al.Kilogram-scale fabrication of a robust olefin-linked covalent organic framework for separating ethylene from a ternary C2 hydrocarbon mixture[J].Journal of the American Chemical Society,2023,145(39):21483-21490.

32 Furukawa H,Yaghi O M.Storage of hydrogen,methane,and carbon dioxide in highly porous covalent organic frameworks for clean energy applications[J].Journal of the American Chemical Society,2009,131(25):8875-8883.

33 Mendoza-Cortes J L,Goddard W A,Furukawa H,et al.A covalent organic framework that exceeds the DOE 2015volumetric target for H2 uptake at 298 K[J].Journal of Physical Chemistry Letters,2012,3(18):2671.

34 Yue L,Wang X,Chen L,et al.In situ interface engineering of highly nitrogen-rich triazine-based covalent organic frameworks for an ultra-stable,dendrite-free lithium-metal anode[J].Energy&Environmental Science,2024,17(3):1117-1131.

35 Zhai L,Li G,Yang X,et al.30 Li+-accommodating covalent organic frameworks as ultralong cyclable highcapacity Li-Ion battery electrodes[J].Advanced Functional Materials,2021,32(9):2108798.

36 He L,Li B,Ma Z,et al.Synergy of first-and second-sphere interactions in a covalent organic framework boosts highly selective platinum uptake[J].Science China Chemistry,2023,66(3):783-790.

37卿文权.有色冶金技术的现状与发展研究[J].中国金属通报,2023(1):4-6.

38付子忠.从矿石和废料中回收有色金属的常用湿法冶金工艺和设备[J].湿法冶金,2011,30(3):175-183.

基本信息:

DOI:10.16026/j.cnki.iea.2024010041

中图分类号:TQ324.8

引用信息:

[1]毛天晖,刘兆菲,张振杰.COF均孔树脂研究和产业化进展[J].离子交换与吸附,2025,41(01):1-13.DOI:10.16026/j.cnki.iea.2024010041.

基金信息:

国家自然科学基金(基金号22001131)

检 索 高级检索

引用

GB/T 7714-2015 格式引文
MLA格式引文
APA格式引文