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金属有机框架(MOF)材料具有高比表面积、高孔隙率、精准的孔道形貌和可调的孔道尺寸等独特性质，在气体分离/净化/存储、非均相催化反应、水处理以及生物医药等领域有着巨大的应用潜能，作为重要的新型功能材料引起了国内外的广泛关注。经过近二十多年的深入研究，在MOF材料的制备方法和物理化学性质等方面已经取得了很大的进展，当前的主要焦点在于如何实现MOF材料的工业化大规模实际应用。然而，MOF材料自身的诸多内在缺陷,尤其是化学不稳定性特别是易水解、较弱的力学强度以及多晶粉末导致难以加工成型等严重制约了其工业应用。在本综述中，我们将对MOF材料实际应用过程中面临的一些主要挑战和最新的对应策略进行简单综述。
Abstract：Metal-organic frameworks(MOFs) have unique properties such as high specific surface area, abundant porosity, as well as rich micropores with precise morphologies and tunable sizes. MOFs have great potential applications in separation, purification and storage of gas, heterogeneous catalysis, water treatment and biomedicines, etc. Therefore, MOFs have attracted ever-growing attention in the past decades. After nearly two decades of intensive investigation, significant progress has been made in preparation of countless kinds of MOFs and their physicochemical properties. The current focus is on how to implement the large-scale industrial applications of MOF materials with promising functionalities as demonstrated at the lab scale. However, many inherent shortcomings of MOF materials have delayed the process of extending MOFs into practical industrial applications. Especially, the following three properties of many MOFs have been the main bottlenecks that are needed to be considered: chemical instability such as vulnerability to hydrolysis, weak mechanical strength, and difficulty in processing into practical material forms due to polycrystalline powders. In this review, we provide a brief overview of these three main challenges facing the practical applications of MOFs and the state-of-the-art strategies that have been reported to address such challenges.
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基本信息:
DOI：10.16026/j.cnki.iea.2023010075
中图分类号:O641.4
引用信息:
[1]陈亿昂,耿玘薇,曹香慧,等.金属有机框架材料工业应用中面临的挑战以及最新应对策略[J].离子交换与吸附,2023,39(01):75-86.DOI:10.16026/j.cnki.iea.2023010075.
基金信息:
国家自然科学基金面上项目(No.52273022)