| 450 | 20 | 26 | 
| 下载次数 | 被引频次 | 阅读次数 | 
以十六烷基三甲基溴化铵(CTAB)改性沸石作为吸附剂,研究了其对水溶液中甲基橙(MO)的吸附行为。用红外光谱(FT-IR)和BET方法对沸石进行了表征。研究表明,CTAB改性沸石对MO的吸附符合Langmuir模型,在pH值为7、温度为298.15K、振荡速度为160r/min时,CTAB改性沸石对MO的最大吸附量为82mg/g。动态吸附实验表明,CTAB改性沸石对MO的吸附动力学可以用准二级动力学方程描述,说明它的吸附机理是一个物理与化学吸附过程。
Abstract:CTAB-modified zeolite was prepared as a cost-effective technology for the removal of Methyl Orange(MO) from wastewater. The modified zeolite was charactered by Fourier-Transform Infrared spectroscopy(FT-IR) and BET technique. The experimental data for both MO systems fitted the Langmuir isotherm model well. The maximum adsorption capacity of MO with CTAB-modified zeolite was 82mg/g with shake speed of 160r/min at 298.15 K and pH 7. The kinetic analysis demonstrated that the adsorption of MO onto CTAB-modified zeolite followed the Pseudo-second-order rate equation, suggesting that the adsorption mechanism was dominated by a physical and chemical adsorption process.
[1]任南琪,周显娇,郭婉茜,等.染料废水处理技术研究进展.化工学报[J].2013,64(1):84-94.
[2]顾鼎言,朱素芬.印染废水处理[M].北京:中国建筑工业出版社,1985,p275.
[3]罗昊进,谭立国.印染废水处理新技术.工业水处理[J].2008,28(3):87-88.
[4]金晓英,陈海斌,王清萍,等.SDBS改性沸石吸附亚甲基蓝的性能研究.水处理技术[J].2009,35(12):58-60.
[5]朱月琴,汪媛.天然染料及其染色.染整技术[J].2007,29(6):14-18.
[6]胥维昌.染料行业废水处理现状和展望.染料工业[J].2002,39(6):35-39.
[7]郑冀鲁,范娟.印染废水脱色技术与理论述评.环境污染治理技术与设备[J].2000,1(5):29-35.
[8]陆朝阳,沈莉莉,张全兴.吸附法处理染料废水的工艺及其机理研究进展.工业水处理[J].2004,24(3):12-16.
[9]余刚,杨志华,祝万鹏,等.染料废水物理化学脱色技术的现状与进展.环境科学[J].1994,15(4):75-79.
[10]庄源益,戴树桂,李彤.生物絮凝剂对水中染料絮凝效果探讨.水处理技术[J].1997,23(6):349-353.
[11]徐向荣,王文华,李华斌.Fenton试剂与染料溶液的反应.环境科学[J].1999,20(3):72-74.
[12]赵永才,孙又山.微电解法脱除水溶性染料废水色度的研究.环境污染与防治[J].1994,16(1):18-21.
[13]马永强.天然沸石在水处理中的应用.山西建筑[J].2004,30(16):120-121.
[14]李工,阚秋斌.含有沸石结构单元体介孔材料的合成及催化性能.化学学报[J].2002,60(5):759-763.
[15]佟小薇,朱义年.沸石改性及其去除水中氨氮的实验研究.环境工程学报[J].2009,3(4):635-638.
[16]孙杨,弓爱君,宋永会,等.沸石改性方法研究进展.无机盐工业[J].2008,40(5):1-4.
[17]曹建劲.沸石改性及其吸附性能研究.化工矿物与加工[J].2002,31(12):10-11.
[18]赵春辉,于衍真,冯岩.沸石的改性与再生及其在水处理中的应用.江苏化工[J].2008,36(4):30-33.
[19]王绪绪,陈旬.沸石分子筛的表面改性技术进展.无机化学学报[J].2002,18(6):541-549.
[20]袁凤英,秦清风.表面活性剂改性沸石及其处理废水研究.太原科技大学学报[J].2005,26(2):157-160.
[21]Zhao Yaping,Gao Tingyao,Jiang Shangying,Cao Dawen.Ammonium removal by modified zeolite from municipal wastewater.Journal of Environmental Sciences[J].2004,16(6):1001-1004.
[22]Li Manni,Zhang Jinglin,Mengkebayaer,Xin Jileho.The study on properties of Na+-Cu2+cation exchange in waste water containing Cl-or F-anion on the Naform clinoptilolite.Acta Scientiae Circumstantiae[J].2001,21(1):93-96.
[23]张增强,孟昭福,张一平.Freundlich动力学方程及其参数的物理意义探析.西北农林科技大学学报(自然科学版)[J].2003,31(5):202-204.
[24]张增强,张一平.几个吸附等温模型热力学参数的计算方法.西北农业大学学报[J].1998,26(2):94-98.
[25]何永祥.天然沸石对水体中甲基橙和亚甲基蓝的吸附研究[D].硕士论文,郑州:郑州大学,2007.
[26]Garcia-Delgado R A,Cotoruelo-Minguez L M,Rodriguez J J.Equilibrium study of single-solute adsorption of anionic surfactants with polymeric XAD resins.Separation Science and Technology[J].1992,27(7):975-987.
[27]Ng E-P,Mintova S.Nanoporous materials with enhanced hydrophilicity and high water sorption capacity.Microporous and Mesoporous Materials[J].2008,114(1/2/3):1-26.
[28]Crini G.Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment.Progress in Polymer Science[J].2005,30(1):38-70.
[29]Gupta V K,Suhas.Application of low-cost adsorbents for dye removal-A review.Journal of Environmental Management[J].2009,90(8):2313-2342.
基本信息:
DOI:10.16026/j.cnki.iea.2015050417
中图分类号:X788;O647.3
引用信息:
[1]李琨琪,晏雅婧,潘远凤,等.用于染料吸附的改性沸石吸附剂:机理及功能表征[J].离子交换与吸附,2015,31(05):417-429.DOI:10.16026/j.cnki.iea.2015050417.
基金信息:
国家自然科学基金(9120513017)